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By David Michael P. Mingos

1. D.M.P. Mingos, J.E. McGrady, A. L. Rohl Moments of Inertia in Cluster and Coordination Compounds 2. M. Drillon, J. Darriet development in Polymetallic Exchange-Coupled platforms, a few Examples in Inorganic Chemistry three. P. Zanello Stereochemical facets linked to the Redox Behaviour of Heterometal Carbonyl Clusters four. R. G. Denning digital constitution and Bonding in Actinyl Ions five. M. Evain, R. Brec a brand new method of Structural Description of advanced Polyhedra Containing Polychalcogenide Anions 6. E. Brese, M. O'Keeffe Crystal Chemistry of Inorganic Nitrides

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Additional resources for Complexes, Clusters and Crystal Chemistry (Structure and Bonding, Volume 79)

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M~ ~ i/N ~Ni ~"I phzp - 15 II . 2 CHCI~ 18 Fig. 19. P. Mingoset al. Figure 17 indicates that it is not valid to describe these structures in terms of the Berry pathway at all. The considerable deviation of points about the reaction coordinate for structures close to the trigonal bipyramid may indicate that the energy hypersurface does not rise sharply in a direction perpendicular to the reaction coordinate in this region of space. In addition, it has been shown [37] that 5-coordinate complexes may lie on a reaction coordinate involving attack by a ligand on a 4-coordinate centre.

5 Concluding Remarks . . . . . . . . . . . . . . . . . . . . . . . . . . 6 References . . . . . . . . . . . . . . . . . . . . . . 76 81 81 84 86 86 87 91 93 97 . . . . . . . . . 99 Structure and Bonding 79 9 Springer-Verlag Berlin Heidelberg 1992 56 Marc Drillon and Jacques Darriet 1 Introduction The chemical and physical properties of polynuclear systems always attract the attention of researchers concerned in inorganic and molecular chemistry, bioinorganics and solid state physics.

Berry RS (1960) J. Chem. Phys. 32:933 29. Rauk A, Allen LC, Mislow K (1972) J. Am. Chem. Soc. 94:3035 30. Kepert DL (t973) Inorg. Chem. 12:1938 31. Muetterties EL (1969) J. Am. Chem. Soc. 91:1636 32. Ugi I, Marquarding D, Klusacek H, Gillespie P, Ramirez F (1971) Acc. Chem. Res. 4:288 33. Meakin P, Muetterties EL, Jesson PJ (1972) J. Am. Chem. Soc. 94:5271 34. Holmes RR, Deiters J (1977) J. Am. Chem. Soc. 99:3318 35. Auf der Heyde TA, Nassimbini L (1984) Inorg. Chem. -B, (1989) J. Am. Chem. Soc.

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