By S. Trippett
Organophosphorus Chemistry offers a entire annual evaluate of the literature. insurance comprises phosphines and their chalcogenides, phosphonium salts, low coordination quantity phosphorus compounds, penta- and hexa-coordinated compounds, tervalent phosphorus acids, nucleotides and nucleic acids, ylides and comparable compounds, and phosphazenes. The sequence might be of price to analyze employees in universities, govt and commercial study businesses, whose paintings consists of using organophosphorus compounds. It offers a concise yet finished survey of an unlimited box of analysis with a large choice of functions, allowing the reader to quickly hold abreast of the newest advancements of their expert components. professional Periodical stories offer systematic and specific evaluate insurance of development within the significant components of chemical study. Written by means of specialists of their professional fields the sequence creates a special provider for the energetic learn chemist, providing normal serious in-depth debts of growth particularly parts of chemistry.
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Extra info for Organophosphorus Chemistry (SPR Organophosphorus Chemistry (RSC)) (v. 9)
43 Me I+ I- -t Li+ (43) 8. R = Me HOCH, -Q HOCH, -' 225'C ~ R\L IR' 0 2 (45) 28 29 S. A. Bone, S. Trippett, and P. J. S. Perkin I , 1977, 80. Hellwinkel and W. Krapp, Chem. , 1977, 110, 693. 31 Quinquecoualent Phosphorus Compounds Me e 2 0‘om Et Me Me (47) A kinetic investigation of the reaction of the phospholens (47) with diethyl peroxide in various solvents supports a mechanism involving rate-determining biphilic attack of the phosphine on the peroxide followed by rapid fragmentation of the resulting p h o ~ p h o r a n eA .
Cowley and R. S. Chem. , 1977, 1 1 1 . J. A. -V. Roschenthaler, and R. Schmutzler, 2. , 1977, 32b, 599. T. Kawashima and N. Inamoto, Bull. Chem. Soc. Japan, 1976,49, 1924. W. Zeiss, Angew. Chem. Internat. , 1976, 15, 555. 35 QuinquecovalentPhosphorus Compounds - M e F o R,NP-NSiK, I I R,SiN-PNR, + (MeCO), R = Me I ‘0 ‘P-NSiR, RN , I’ Me I N-PNR, R, Si (34) 0 , ) RzN Me: Me R . f-- Me,P-PMe, II + HF FCC1, Me,FP-NSiMe, I L c NSiMe, (Me, Si),N Me,SiN (37) Me (Me3si)2N,p/N\ \ yp=NSiMe, + MeN=P(NMe,), t Me, SiN-PFMe, __t a,/ P(NMe2)3 Me, SiN SiMe, (38) (37),25 and (38),26 the first penta-aminophosphorane.
C. Falk, J. Org. , 1976,41, 2928. S. -C. Lkpine, G. Aranda, and G. S. Chem. , 1976, 747. R. Neidlein and R. Mosebach, Arch. , 1976, 309, 707 (Chem. , 1977, 86, 106479). E. T. Michalski, M. Pakulski, and A. Skowronska, TetrahedronLetters, 1977, 2019. g. ~~ With phosphorus trichloride and triethylamine in dimethylacetamide these acids give the phosphoranes (86). H 47 48 49 S. A. Bone, S. Trippett, and P. J. S. Perkin I, 1977, 437. M. Brazier, D. Houalla, A. Munoz,and R. S. Chem. ,1976,730. B. Garrigues, A.