By M. B. Maple, Ø. Fischer (auth.), Prof. M. Brian Maple, Prof. Øystein Fischer (eds.)
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Extra resources for Superconductivity in Ternary Compounds II: Superconductivity and Magnetism
30], in contrast to the other three polytypes. 19,69] evidently give rise to changes in the electronic and/or phonon properties which are unfavorable to the occurrence of superconductivity. 73], but the details of the crystal structures are not yet known. 70] has reported the occurrence of MT4B4 compounds in the eight systems (V, Gd, Tb, Dy, Ho, Er, Tm, Vb)-Os-B. 67]; this suggests the existence of yet another polytype of LuRh 4B4 . 74] which among ternary borides are second only to those of the MT 4B4 phases.
Ultimately, whether the apparent crystallographic clustering is important physically should be reflected in pronounced anisotropy in the physical properties where the anisotropy must exhibit the symmetry of the cluster network. 29,140]. Physically important clustering behavior has been found to be correlated with the occurrence of significant charge transfer from/to the clusters within the structure. 6,141-146]. 1, we have alluded to work which has suggested that abrupt composition-induced charge transfer between the B2 dimers and the transition metal sublattice in M(Rh1_xTx)4B4 compounds is responsible for the abrupt composition-induced Tc anomalies observed in these systems.
70] has reported the occurrence of MT4B4 compounds in the eight systems (V, Gd, Tb, Dy, Ho, Er, Tm, Vb)-Os-B. 67]; this suggests the existence of yet another polytype of LuRh 4B4 . 74] which among ternary borides are second only to those of the MT 4B4 phases. 75] which also has some similar structural features as will be noted below. 27,74,76]. 76]. 77]. 74 ~) as in the MT4B4 compounds and are located between the Lu-Ru planes. , parallel to the b-axis); this is in contrast to the MT4B4 compounds, in which the B2 dimers are isolated from each other.