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3. Cyclization of 6C-Substituted Hexopyranoses . . . . . . 4. Action of Acids on Hexoses and Their Derivatives . . . . . . . . . . 5. Thermal Degradation of Polysaccharides, Oligosaccharides, and ..................... Hexoses . . . . . . . . . 6. Miscellaneous Methods . . . . . . . 7. Total Synthesis from Acrolein ....................................... 111. General Properties of 1,6-Anhydrohexopyranoses ........................ IV. Reactions of 1,6-Anhydrohexopyranoses.

Chem. , 48654871 (1957). “Immunopolysaccharides. ranosyl3-0-methyl-D-glucose by Betacoccus arabinosaceous,” S. A. Barker, E. J. Bourne, P. M . Grant, and M. Stacey,]. Chem. , 601-604 (1958). “The Polyhydric Alcohols; Acyclic Polyhydric Alcohols,” E. J. Bourne, in “Handbuch der Pflanzenphysiologie,” W. , Springer Verlag, Berlin, 1958, pp. 345-362. “Studies of Trifluoroacetic Acid. Part XIV, Reaction of Acyl Trifluoroacetates with 1:6-Di-0-benzoyl-2 :4-3 : 5-di-0-methylene-D-glucitol,” E. J. Bourne, J.

Worth, Phytochemisiry, 6 , 4 2 3 4 3 1 (1967). “Professor T. S. Moore-Obituary,” E. J. Bourne, Nature, 214, 1063 (1967). “Ring Scission of Cyclic Acetals. Part 111, Reaction of Acetyl Trifluoroacetate with 1,3:2,5 :4,6Tri-O-methylene-~-mannitol,” T. G. Bonner, E. J. Bourne, and D. Lewis, J . Chem. , C , 2321-2336 (1967). “The Formation, under Kinetic Control, of a New Monoacetal (2,3-O-Butylidene-~Glucitol) from D-Glucitol and n-Butyraldehyde,” T. G. Bonner, E. J. Bourne, P. J. V. Cleare, and D.

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